2.2]decane Main and defining the geometry in the exocyclic double bond. The activation energies of development in the vinyl-gold intermediates were being calculated and discovered a silyl enol ether with an unprotected indole moiety as an acceptable precursor for that Toste cyclization. This six-step synthesis didn't involve any nonstrategic redox
2.two]decane Main and defining the geometry of your exocyclic double bond. The activation energies of formation on the vinyl-gold intermediates ended up calculated and disclosed a silyl enol ether having an unprotected indole moiety as a suitable precursor for your Toste cyclization. This 6-phase synthesis did not include any nonstrategic redox man
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